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冷變形及退火對5E06鋁板晶間腐蝕性能的影響
發布人:上海艾荔艾金屬材料有限公司www.jshcn.cn
更新時間:2015-08-25
采用晶間腐蝕性能測試及透射電鏡研究冷變形及退火對5E06鋁板晶間腐蝕性能的影響規律。
冷變形及退火對5E06鋁板晶間腐蝕性能的影響Effect of cold deformation and annealing on intergranular
corrosion property of 5E06 aluminium alloy plates
采用晶間腐蝕性能測試及透射電鏡研究冷變形及退火對5E06鋁板晶間腐蝕性能的影響規律。結果發現:5E06鋁板的晶間腐蝕性能與β相的分布、形貌和析出量密切相關。當冷變形量低于40%時,β相較易在晶界析出達到連續而使合金晶間腐蝕性能惡化;當變形量增加到55%以上時,經穩定化退火后β相在晶界不容易連續,5E06鋁板晶間腐蝕性能良好。進一步的敏化試驗表明,經55%~80%冷變形的5E06鋁板在120
℃穩定化退火的效果并不理想,而220℃的穩定化退火由于獲得了比較均勻的亞晶組織且β相在晶界/亞晶界斷續分布并一定程度上降低基體中鎂原子的過飽和度,可使穩定化退火態5E06鋁板在長期使用過程中晶間腐蝕性能不發生明顯退化。
The effects of cold deformation and annealing on the
intergranular corrosion property of 5E06 aluminium alloy plates were
investigated by intergranular corrosion property tests and transmission electron
microscope (TEM). The results show that the intergranular corrosion property of
5E06 aluminium alloy plates has close relationship with the distribution,
morphology and quantity of β phase. When the cold deformation is under 40%, β
phase is easy to precipitate continuously at grain boundaries which will worsen
the intergranular corrosion property. When the cold deformation exceeds 55%, β
phase is not easy to achieve succession after stabilizing annealing and the 5E06
aluminum alloy plates have favorable intergranular corrosion property.
Sensitization tests indicate that the effect of stabilizing at 120 ℃ is not
desirable for 5E06 aluminum alloy plates at cold deformation of 55%-80%, whereas
the aluminum alloy plates annealed at 220 ℃ can obtain homogeneous subgrains and
β phase distributes discretely at grain boundaries and subgrain boundaries which
can reduce the degree of supersaturation to some extent. Therefore, the
intergranular corrosion property of 5E06 aluminum alloy plates at stabilizing
annealing states won’t degenerate obviously in the long-term using
process.
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